2008-01-24 Villarreal -:- Barcelona

2008-01-31 Barcelona -:- Villarreal

2015-02-11 Barcelona 3:1 Villarreal

2015-03-04 Villarreal 1:3 Barcelona

2001-12-15 Villarreal -:- Barcelona

2002-04-26 Barcelona 4:1 Villarreal

2002-11-08 Barcelona -:- Villarreal

2003-04-04 Villarreal -:- Barcelona

2003-11-21 Villarreal 2:1 Barcelona

2004-04-02 Barcelona -:- Villarreal

2005-01-08 Villarreal -:- Barcelona

2005-05-21 Barcelona 3:3 Villarreal

2005-12-03 Villarreal -:- Barcelona

2006-04-13 Barcelona -:- Villarreal

2006-11-25 Barcelona -:- Villarreal

2007-04-22 Villarreal -:- Barcelona

2007-10-20 Villarreal 3:1 Barcelona

2008-03-09 Barcelona 1:2 Villarreal

2008-12-21 Villarreal 1:2 Barcelona

2009-05-10 Barcelona 3:3 Villarreal

2010-01-02 Barcelona 1:1 Villarreal

2010-05-01 Villarreal 1:4 Barcelona

2011-08-29 Barcelona -:- Villarreal

2012-01-28 Villarreal -:- Barcelona

2013-12-14 Barcelona 2:1 Villarreal

2014-04-27 Villarreal 2:3 Barcelona

2014-08-31 Villarreal -:- Barcelona

2015-02-01 Barcelona 3:2 Villarreal

2015-11-08 Barcelona -:- Villarreal

2016-03-20 Villarreal 2:2 Barcelona

2017-01-08 Villarreal 1:1 Barcelona

2017-05-06 Barcelona 4:1 Villarreal

2017-12-10 Villarreal -:- Barcelona

2018-05-09 Barcelona 5:1 Villarreal

2018-12-02 Barcelona -:- Villarreal

2019-04-02 Villarreal 4:4 Barcelona

2019-09-24 Barcelona 2:1 Villarreal

2020-07-05 Villarreal 1:4 Barcelona

2020-09-27 Barcelona -:- Villarreal

2021-04-25 Villarreal 1:2 Barcelona

2021-11-27 Villarreal 1:3 Barcelona

2022-05-22 Barcelona -:- Villarreal

2022-10-20 Barcelona -:- Villarreal

2023-02-12 Villarreal -:- Barcelona

2023-08-27 Villarreal 3:4 Barcelona

2024-01-27 Barcelona 3:5 Villarreal

2024-09-22 Villarreal 1:5 Barcelona

2025-05-18 Barcelona 2:3 Villarreal

2025-12-21 Villarreal -:- Barcelona

2026-02-28 Barcelona 4:1 Villarreal